Product ID:ETHYL ETHANOATE ACETIC ACID ETHYL ESTER, EX
MSDS Date:10/27/1987
FSC:6810
NIIN:00N018364
MSDS Number: BKZRK

EM SCIENCE

480 DEMOCRAT RD
GIBBSTOWN, NJ 08027
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 609-354-9200

Cage: DO242

EM SCIENCE, A DIVISION OF EM INDUSTRIES

70 GIBBSTOWN, NJ 08027 US

Telephone: 856-423-6300

Cage: 0GDF9

OR MISTS TO THE ATMOSPHERE OCCURS.

RTECS: 9999999ZZ

(LIALH*2 + 2-CHLOROMETHYL FURAN); OLEUM.

RTECS: 9999999ZZ

PRESS TYPE) UNDER SPECIFIED CNDTNS (SEE YOUR SFTY

RTECS: 9999999ZZ

CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.

RTECS: 9999999ZZ

SUDDEN INGRESS OF AIR, OR OUTSIDE PROCESS EQUIP

RTECS: 9999999ZZ

ETHYL ACETATE (SARA III)

CAS: 141-78-6

RTECS: AH5425000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50:(ORAL RAT) 5620 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES DERMATITIS & SEVERE DEFATTING
OF SKIN FROM EXCESSIVE CONT. HIGH VAPOR CONC CAUSE HEADACHE,
NARCOSIS, IRRIT OF EYES, NOSE, THROAT (SEVERE EYE IRRIT AT 400 PPM)
& UNCONSCIOUSNESS. HIGH CONC CAN C AUSE CONGESTION OF THE LIVER &
KIDNEYS.INGESTION MAY CAUSE HEADACHE, NAUSEA, NARCOSIS &
UNCONSCIOUSNESS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:RESPIRATORY, KIDNEY, LIVER, SKIN &
BLOOD DISORDER CONDITIONS.

First Aid:GET MD FOR ALL CASES OF OVEREXPOSURE. SKIN: WASH THOROUGHLY
W/SOAP & WATER. EYE:IMMEDIATELY FLUSH THOROUGHLY W/WATER FOR AT
LEAST 15 MINUTES. INHAL:REMOVE TO FRESH AIR; GIVE ARTIFICIAL
RESPIRATION IF BREATHING HAS STOPPED. INGEST:IF CONSCIOUS, GIVE
MILK OR WATER & INDUCE VOMITING. REMOVE CONTAMINATED CLOTHING &
WASH BEFORE REUSE.

Flash Point Method:TCC
Flash Point:24.0F,-4.4C
Lower Limits:2.2%
Upper Limits:11%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM. WATER SPRAY
TO COOL EXPOSED CONTAINERS, DISPERSE VAPORS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ. VAP CAN TRAVEL
DISTANCES TO IGNIT SOURCE & FLASH BACK. HOT ORG CHEM VAPS/MISTS ARE
SUSCEPTIBLE TO SUDDEN SPONT COMBUST WHEN (SEE SUPP DATA)

Spill Release Procedures:ELIMINATE IGNITION SOURCES; DIKE SPILL. TAKE
UP W/ABSORBENT & CONTAINERIZE FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL AREA AWAY FROM IGNIT
SOURCES & OXIDIZERS. KEEP CONTR CLSD. DO NOT GET IN EYES, ON SKIN
OR ON CLOTHING. DO NOT BREATHE VAPOR.
Other Precautions:RETAINED RESIDUE MAY MAKE EMPTY CONTAINERS HAZARDOUS;
USE CAUTION! DO NOT TAKE INTERNALLY. TEST ON LAB ANIMALS INDICATE
MATERIAL MAY PRODUCE ADVERSE MUTAGENIC EFFECTS.

Respiratory Protection:IF WORKPLACE EXPOS LIMIT(S) OF PROD OR ANY
COMPONENT IS EXCEEDED (SEE TLV/PEL), A NIOSH/MSHA APPRVD AIR
SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL. OSHA
REGS ALSO PERMIT OTHER NIOSH /MSHA APPRVD RESPS (NEG (SEE INGRED 5)
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
FUME HOOD OR W/ADEQUATE VENTILATION.
Protective Gloves:BUTYL RUBBER, CPE OR EQUIVALENT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & SAFETY EQUIPMENT SHOULD BE
READILY AVAILABE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ:MIXED W/AIR. IGNIT MAY OCCUR AT TEMPS BELOW PUBLISHED
AUTOIGNIT OR IGNIT TEMPS. IGNIT TEMPS DECREASE W/ INCREASING VAP
VOL & VAP/AIR CONT TIME & ARE INFLUENCED BY PRESS CHANGES. IGNIT
MAY OC CUR AT TYPICAL ELEVATED TEMP PROCESS CNDTNS, ESPECIALLY IN
PROCESS OPERATING UNDER VACUUM IF SUBJECTED TO (SEE INGRED 2)

HCC:F3
Boiling Pt:B.P. Text:171F,77C
Melt/Freeze Pt:M.P/F.P Text:-118F,-84C
Vapor Pres:75
Vapor Density:3.04
Spec Gravity:0.9018
Evaporation Rate & Reference:7.5 (BUTYL ACETATE=1)
Solubility in Water:7.4%
Appearance and Odor:CLEAR, COLORLESS LIQUID; CHARACTERISTIC SWEET ODOR.
Percent Volatiles by Volume:99+

Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZERS, STRONG ALKALIES & NITRATES.
Stability Condition to Avoid:CONT W/IGNIT SOURCES; HEAT. IGNITES ON
CONT W/POTASSIUM TERT-BUTOXIDE. VIOLENT RXN W/CHLOROSULFONIC ACID;
(SEE INGRED 4)
Hazardous Decomposition Products:COX.

Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE W/ALL CURRENT
LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.